Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate
نویسندگان
چکیده
In the title mononuclear complex, [Zn(ClO(4))(C(17)H(11)N(3)O)(2)]ClO(4), the Zn(II) ion is coordinated in a distorted octa-hedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP ligand. Within the mol-ecule there is a weak π-π inter-action between the pyridine ring of the bidentate ligand and the 1,10-phenanthroline ring system of the tridendate ligand with a centroid-centroid distance of 3.6383 (19) Å.
منابع مشابه
Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)
In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal-bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short inter-molecular distances [3.627 (4)-3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the exis...
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In the title mononuclear complex, [CuCl(2)(C(17)H(11)N(3)O)], the Cu(II) ion is in a distorted square-pyramidal coordination environment. The crystal structure is stabilized by various π-π stacking inter-actions in which the benzene ring, a pyridine ring and the five-membered CuN(2)C(2) ring are involved. The centroid-centroid distances range from 3.5631 (15) to 3.5666 (16) Å.
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